We have just seen a modification on the Sticky Shed Syndrome (SSS) failure mode. This is a case where the back-coat of the tape is turning to powder. The oxide was brown but yet it left a black, non-sticky accumulation of powder on the reproduce head. This accumulation would drastically reduce the high frequency response of the system due to spacing loss. We did bake the tape and we’re not sure that helped significantly, although it did not appear to make the problem worse. We would NOT recommend baking these tapes in the future. Ultimately, Pellon wiping of the mag coat during transfer after several pre-wipes for the length of the tape solved this.
Agfa PEM-526 exhibited this odd behaviour. The tape was recorded in 1990.
There is also a discussion about PEM-469 showing similar behaviour here.
For a current list of degrading analog tapes, click here.